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58,80 €ISBN 978-3-8191-0714-6Paperback184 Seiten98 Abbildungen327 g24 x 17 cmEnglischDissertation
November 2026
Neuerscheinung
Sascha Hintenlang
Implementing A New Comonomer into the High-Pressure Polymerization with Ethene
In this work, the implementation of a new comonomer vinyl neodecanoate into the free radical high-pressure polymerization with ethene was investigated. The following four topics were of interest, always with a focus on having data and knowledge at process temperatures and pressures:
- thermophysical properties (compressibility, density, thermal expansion coefficient, and the change in heat capacity with pressure) of the new comonomer at conditions close to the large-scale process conditions
- phase behavior of the co- and terpolymerization system
- process safety with the focus on the comonomer’s effect on inherent safety
- copolymerization kinetics of vinyl neodecanoate and ethene with a focus on reactivity ratios and transfer to vinyl neodecanoate
Schlagwörter: Hochdruck; Ethen; LDPE; Polymerisation; Comonomer; Scale-up
Darmstädter Schriftenreihe der Polymerisationstechnik
Herausgegeben von Prof. Dr. Markus Busch, Darmstadt
Band 36
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